Entropy Equation
1. The problem is to understand the entropy equation in thermodynamics.
2. Entropy ($S$) is a measure of the disorder or randomness in a system.
3. The fundamental formula for entropy change ($\Delta S$) when heat ($Q$) is transferred reversibly at temperature ($T$) is:
$$\Delta S = \frac{Q_{rev}}{T}$$
4. Important rules:
- $Q_{rev}$ is the heat exchanged in a reversible process.
- Temperature $T$ must be in Kelvin.
5. For a system going from state 1 to state 2, the total entropy change is:
$$\Delta S = S_2 - S_1 = \int_{1}^{2} \frac{dQ_{rev}}{T}$$
6. In statistical mechanics, entropy is related to the number of microstates ($\Omega$) by Boltzmann's equation:
$$S = k_B \ln \Omega$$
where $k_B$ is Boltzmann's constant.
7. Summary: Entropy quantifies disorder and is calculated by heat transfer over temperature or by counting microstates.
Final answer: The entropy change formula is $$\Delta S = \frac{Q_{rev}}{T}$$ for reversible processes.