Enthalpy Change Eb606C
1. **State the problem:** Calculate the enthalpy change when 50 g of ice at -10°C is heated to water at 30°C.
2. **Given data:**
- Mass, $m = 50$ g
- Initial temperature of ice, $T_i = -10^\circ C$
- Final temperature of water, $T_f = 30^\circ C$
- Specific heat capacity of ice, $c_{ice} = 2.09$ J/g$^\circ$C
- Specific heat capacity of water, $c_{water} = 4.184$ J/g$^\circ$C
- Heat of fusion of ice, $\Delta H_{fusion} = 6.01$ kJ/mol
- Molar mass of water, $M = 18.015$ g/mol
3. **Process steps:**
- Heat ice from -10°C to 0°C
- Melt ice at 0°C to water
- Heat water from 0°C to 30°C
4. **Calculate heat to warm ice from -10°C to 0°C:**
$$q_1 = m \times c_{ice} \times \Delta T = 50 \times 2.09 \times (0 - (-10)) = 50 \times 2.09 \times 10 = 1045 \text{ J}$$
5. **Calculate heat to melt ice at 0°C:**
- Number of moles of ice:
$$n = \frac{m}{M} = \frac{50}{18.015} \approx 2.776 \text{ mol}$$
- Heat for fusion:
$$q_2 = n \times \Delta H_{fusion} = 2.776 \times 6.01 \times 1000 = 16679.76 \text{ J}$$
6. **Calculate heat to warm water from 0°C to 30°C:**
$$q_3 = m \times c_{water} \times \Delta T = 50 \times 4.184 \times (30 - 0) = 50 \times 4.184 \times 30 = 6276 \text{ J}$$
7. **Total heat absorbed:**
$$q_{total} = q_1 + q_2 + q_3 = 1045 + 16679.76 + 6276 = 24000.76 \text{ J}$$
8. **Convert total heat to kilojoules:**
$$q_{total} = \frac{24000.76}{1000} = 24.001 \text{ kJ}$$
**Final answer:** The enthalpy change is approximately **24.0 kJ**.
**Heating curve description:**
- From -10°C to 0°C: temperature of ice increases (solid phase)
- At 0°C: phase change from ice to water (melting)
- From 0°C to 30°C: temperature of water increases (liquid phase)