Schrodinger Parabolic 17308A
1. **Problem Statement:** Show that the Schrödinger equation
$$-\frac{\hbar^2}{2m} \frac{\partial^2 \phi(x,t)}{\partial x^2} = -i \hbar \frac{\partial \phi(x,t)}{\partial t}$$
is a parabolic partial differential equation.
2. **Recall the general form of second-order PDEs:**
$$A \frac{\partial^2 u}{\partial x^2} + 2B \frac{\partial^2 u}{\partial x \partial t} + C \frac{\partial^2 u}{\partial t^2} + \text{lower order terms} = 0$$
The classification depends on the discriminant $D = B^2 - AC$:
- Elliptic if $D < 0$
- Parabolic if $D = 0$
- Hyperbolic if $D > 0$
3. **Rewrite Schrödinger equation:**
$$-\frac{\hbar^2}{2m} \frac{\partial^2 \phi}{\partial x^2} + i \hbar \frac{\partial \phi}{\partial t} = 0$$
4. **Identify coefficients:**
- $A = -\frac{\hbar^2}{2m}$
- $B = 0$ (no mixed derivative term)
- $C = 0$ (no second derivative in time)
5. **Calculate discriminant:**
$$D = B^2 - AC = 0^2 - \left(-\frac{\hbar^2}{2m}\right)(0) = 0$$
6. **Conclusion:** Since $D=0$, the Schrödinger equation is a parabolic PDE.
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7. **Problem Statement:** Solve the time-dependent Schrödinger equation for a free particle:
$$-\frac{\hbar^2}{2m} \frac{\partial^2 \phi}{\partial x^2} = -i \hbar \frac{\partial \phi}{\partial t}$$
8. **Rewrite:**
$$i \hbar \frac{\partial \phi}{\partial t} = -\frac{\hbar^2}{2m} \frac{\partial^2 \phi}{\partial x^2}$$
9. **Use separation of variables:** Assume
$$\phi(x,t) = X(x) T(t)$$
Substitute into equation:
$$i \hbar X(x) \frac{dT}{dt} = -\frac{\hbar^2}{2m} T(t) \frac{d^2 X}{dx^2}$$
Divide both sides by $X(x) T(t)$:
$$i \hbar \frac{1}{T} \frac{dT}{dt} = -\frac{\hbar^2}{2m} \frac{1}{X} \frac{d^2 X}{dx^2} = E$$
where $E$ is a separation constant (energy eigenvalue).
10. **Solve spatial part:**
$$\frac{d^2 X}{dx^2} + \frac{2mE}{\hbar^2} X = 0$$
General solution:
$$X(x) = A e^{i k x} + B e^{-i k x}$$
where
$$k = \frac{\sqrt{2mE}}{\hbar}$$
11. **Solve temporal part:**
$$i \hbar \frac{dT}{dt} = E T$$
$$\Rightarrow \frac{dT}{dt} = -\frac{i E}{\hbar} T$$
Solution:
$$T(t) = C e^{-i E t / \hbar}$$
12. **Combine solutions:**
$$\phi(x,t) = \left(A e^{i k x} + B e^{-i k x}\right) e^{-i E t / \hbar}$$
13. **Interpretation:** This represents a free particle wave function as a superposition of plane waves with energy $E$ and wave number $k$.
**Final answer:** The Schrödinger equation is parabolic, and its general free particle solution is
$$\phi(x,t) = \left(A e^{i k x} + B e^{-i k x}\right) e^{-i E t / \hbar}$$
where $k = \frac{\sqrt{2mE}}{\hbar}$.