Oxidation Number 761845
1. The problem is to calculate the oxidation number of an element in a compound.
2. The oxidation number (or state) is a measure of the degree of oxidation of an atom in a chemical compound. It is assigned based on a set of rules:
- The oxidation number of an element in its elemental form is 0.
- The oxidation number of a monatomic ion equals the charge of the ion.
- Oxygen usually has an oxidation number of -2, except in peroxides where it is -1.
- Hydrogen usually has an oxidation number of +1 when bonded to nonmetals and -1 when bonded to metals.
- The sum of oxidation numbers in a neutral compound is 0; in a polyatomic ion, it equals the ion charge.
3. To calculate the oxidation number of a specific element, assign known oxidation numbers to other atoms and solve for the unknown using the sum rule.
4. For example, in H2SO4:
- Hydrogen (H) is +1.
- Oxygen (O) is -2.
- Let sulfur (S) be x.
5. The sum of oxidation numbers is 0:
$$2(+1) + x + 4(-2) = 0$$
6. Simplify:
$$2 + x - 8 = 0$$
7. Solve for x:
$$x = 8 - 2 = 6$$
8. Therefore, the oxidation number of sulfur in H2SO4 is +6.
This method applies generally to find oxidation numbers in compounds.