Hydrate Water
1. The problem involves determining the number of water molecules of hydration, $n$, in the compound $\text{MgSO}_4 \cdot n \text{H}_2\text{O}$.
2. Given data: 47.2% water content by mass, and the mole ratio $\frac{6}{120} = 0.05$ moles.
3. The chemical equation is:
$$\text{MgSO}_4 \cdot n \text{H}_2\text{O} \rightarrow \text{MgSO}_4 + n \text{H}_2\text{O}$$
4. To find $n$, use the formula for percent composition by mass:
$$\% \text{water} = \frac{n \times M_{\text{H}_2\text{O}}}{M_{\text{MgSO}_4 \cdot n \text{H}_2\text{O}}} \times 100$$
where $M_{\text{H}_2\text{O}} = 18$ g/mol and $M_{\text{MgSO}_4} = 120$ g/mol.
5. The molar mass of the hydrate is:
$$M_{\text{MgSO}_4 \cdot n \text{H}_2\text{O}} = 120 + 18n$$
6. Substitute the given percent water (47.2%) into the equation:
$$47.2 = \frac{18n}{120 + 18n} \times 100$$
7. Simplify and solve for $n$:
$$0.472 = \frac{18n}{120 + 18n}$$
Multiply both sides by $120 + 18n$:
$$0.472(120 + 18n) = 18n$$
$$56.64 + 8.496n = 18n$$
$$56.64 = 18n - 8.496n = 9.504n$$
$$n = \frac{56.64}{9.504} = 5.96 \approx 6$$
8. The calculated $n$ is approximately 6, indicating the hydrate is $\text{MgSO}_4 \cdot 6 \text{H}_2\text{O}$.
9. The given $n=7$ might be a rounding or experimental value, but calculation shows $n \approx 6$.
Final answer: $n = 6$ water molecules of hydration.